An automotive battery is a rechargeable battery that supplies electrical energy to a motor vehicle. It is also known as an SLI battery (starting-lighting-ignition)  and its main purpose is to start the engine. Once the engine is running, power for the car's electrical systems is supplied by the alternator. Typically, starting discharges less than three per cent of the battery capacity. SLI batteries are designed to release a high burst of current and then be quickly recharged. They are not designed for deep discharge, and a full discharge can reduce the battery's lifespan.
As well as starting the engine an SLI battery supplies the extra power necessary when the vehicle's electrical requirements exceed the supply from the charging system. It is also a stabilizer, evening out potentially damaging voltage spikes. While the engine is running, most of the power is provided by the alternator, which includes a voltage regulator to keep the output between 13.5 and 14.5 V. Modern SLI batteries are lead-acid type, using six series-connected cells to provide a nominal 12 volt system (in most passenger vehicles and light trucks), or twelve cells for a 24 volt system in heavy trucks or earth-moving equipment, for example.
Battery electric vehicles are powered by a high-voltage electric vehicle battery, but they usually have an automotive battery as well, so that they can use standard automotive accessories which are designed to run on 12 V.
Early cars did not have batteries, as their electrical systems were limited. A bell was used instead of an electric horn, headlights were gas-powered, and the engine was started with a crank. Car batteries became widely used around 1920 as cars became equipped with electric starters. The sealed battery, which did not require refilling, was invented in 1971.
The first starting and charging systems were designed to be 6-volt and positive-ground systems, with the vehicle's chassis directly connected to the positive battery terminal. Today, all road vehicles have a negative ground system. The negative battery terminal is connected to the car's chassis.
The Hudson Motor Car Company was the first to use a standardized battery in 1918 when they started using Battery Council International batteries. BCI is the organization that sets the dimensional standards for batteries.
Cars used a 6 V electrical system, and so had 6 V batteries until the mid-1950s. The changeover from 6 to 12 V happened when bigger engines with higher compression ratios required more electrical power to start. Smaller cars, which required less power to start stayed with 6 V longer, for example the Volkswagen Beetle in the mid-1960s and the Citroën 2CV in 1970.
In the 1990s a 42V electrical system standard was proposed. It was intended to allow more powerful electrically driven accessories, and lighter automobile wiring harnesses. The availability of higher-efficiency motors, new wiring techniques and digital controls, and a focus on hybrid vehicle systems that use high-voltage starter/generators has largely eliminated the push for switching the main automotive voltages.
Batteries are typically made of six galvanic cells in a series circuit. Each cell provides 2.1 volts for a total of 12.6 volts at full charge. Each cell of a lead storage battery consists of alternate plates of lead (cathode) and lead coated with lead dioxide (anode) immersed in an electrolyte of sulfuric acid solution. The actual standard cell potential is obtained from the standard reduction potentials. This causes a chemical reaction that releases electrons, allowing them to flow through conductors to produce electricity. As the battery discharges, the acid of the electrolyte reacts with the materials of the plates, changing their surface to lead sulfate. When the battery is recharged, the chemical reaction is reversed: the lead sulfate reforms into lead dioxide. With the plates restored to their original condition, the process may be repeated.
Some vehicles use other starter batteries. the 2010 Porsche 911 GT3 RS has a lithium-ion battery as an option to save weight. Heavy vehicles may have two batteries in series for a 24 V system or may have series-parallel groups of batteries supplying 24 V.
Heat is the primary cause of battery failure as it accelerates corrosion inside the battery.
A vehicle with a flat battery can be jump started by the battery of another vehicle or by a portable battery booster, after which a running engine (but running faster than idle speed) will continue to charge the battery.
Sulfation occurs when the electrodes become coated with a hard layer of lead sulfate which weakens the battery. It occurs when a battery is not fully charged and remains discharged. Sulfated batteries should be charged slowly to prevent damage.
SLI batteries are not designed for deep discharge, and their life is reduced when subjected to this.
Car batteries using lead-antimony plates require regular topping-up with pure water to replace water lost due to electrolysis and evaporation. By changing the alloying element to calcium, more recent designs have reduced the rate of water loss. Modern car batteries have reduced maintenance requirements, and may not provide caps for addition of water to the cells. Such batteries include extra electrolyte above the plates to allow for losses during the battery life.
Some battery manufacturers include a built-in hydrometer to show the state of charge of the battery.
The primary wear-out mechanism is the shedding of active material from the battery plates, which accumulates at the bottom of the cells and which may eventually short-circuit the plates. This can be substantially reduced by enclosing one set of plates in plastic separator bags, made from a permeable material. This allows the electrolyte and ions to pass through, but keeps the sludge build up from bridging the plates.
Battery recycling of automotive batteries reduces the need for resources required for manufacture of new batteries, diverts toxic lead from landfills, and prevents risk of improper disposal. Once a lead acid battery ceases to hold a charge, it is deemed a used lead acid battery (ULAB), which is classified as hazardous waste under the Basel Convention. The 12-volt car battery is the most recycled product in the world, according to the United States Environmental Protection Agency. In the U.S. alone, about 100 million auto batteries a year are replaced, and 99 percent of them are turned in for recycling. However the recycling may be done incorrectly in unregulated environments. As part of global waste trade ULABs are shipped from industrialized countries to developing countries for disassembly and recuperation of the contents. About 97 per cent of the lead can be recovered. Pure Earth estimates that over 12 million third world people are affected by lead contamination from ULAB processing.