Mole Fraction

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## Properties

## Related quantities

### Mass fraction

### Molar mixing ratio

#### Mixing binary mixtures with a common component to form ternary mixtures

### Mole percentage

### Mass concentration

### Molar concentration

### Mass and molar mass

## Spatial variation and gradient

## References

This article uses material from the Wikipedia page available here. It is released under the Creative Commons Attribution-Share-Alike License 3.0.

Mole Fraction

In chemistry, the **mole fraction** or **molar fraction** (* x_{i}*) is defined as the amount of a constituent (expressed in moles),

The sum of all the mole fractions is equal to 1:

The same concept expressed with a denominator of 100 is the **mole percent** or **molar percentage** or **molar proportion** (**mol%**).

The mole fraction is also called the **amount fraction**.^{[1]} It is identical to the **number fraction**, which is defined as the number of molecules of a constituent *N _{i}* divided by the total number of all molecules

The National Institute of Standards and Technology of the United States prefers the term **amount-of-substance fraction** over mole fraction because it does not contain the name of the unit mole.^{[4]}

Whereas mole fraction is a ratio of moles to moles, molar concentration is a quotient of moles to volume.

The mole fraction is one way of expressing the composition of a mixture with a dimensionless quantity; mass fraction (percentage by weight, wt%) and volume fraction (percentage by volume, vol%) are others.

Mole fraction is used very frequently in the construction of phase diagrams. It has a number of advantages:

- it is not temperature dependent (such as molar concentration) and does not require knowledge of the densities of the phase(s) involved
- a mixture of known mole fraction can be prepared by weighing off the appropriate masses of the constituents
- the measure is
*symmetric*: in the mole fractions*x*= 0.1 and*x*= 0.9, the roles of 'solvent' and 'solute' are reversed. - In a mixture of ideal gases, the mole fraction can be expressed as the ratio of partial pressure to total pressure of the mixture
- In a ternary mixture one can express mole fractions of a component as functions of other components mole fraction and binary mole ratios:

Differential quotients can be formed at constant ratios like those above:

or

Ratios X, Y, Z of mole fractions can be written for ternary and multicomponent systems:

These can be used for solving pde like:

or

This equality can be rearranged to have differential quotient of mole amounts or fractions on one side.

or

Mole amounts can be eliminated by forming ratios:

Thus the ratio of chemical potentials becomes:

Similarly the ratio for the multicomponents system becomes

The mass fraction *w _{i}* can be calculated using the formula

where *M _{i}* is the molar mass of the component

Replacing the expression of the molar mass:

The mixing of two pure components can be expressed introducing the amount or molar mixing ratio of them . Then the mole fractions of the components will be:

The amount ratio equals the ratio of mole fractions of components:

due to division of both numerator and denominator by the sum of molar amounts of components. This property has consequences for representations of phase diagrams using, for instance, ternary plots.

Mixing binary mixtures with a common component gives a ternary mixture with certain mixing ratios between the three components. These mixing ratios from the ternary and the corresponding mole fractions of the ternary mixture x_{1(123)}, x_{2(123)}, x_{3(123)} can be expressed as a function of several mixing ratios involved, the mixing ratios between the components of the binary mixtures and the mixing ratio of the binary mixtures to form the ternary one.

Multiplying mole fraction by 100 gives the mole percentage, also referred as amount/amount percent (abbreviated as n/n%).

The conversion to and from mass concentration *? _{i}* is given by:

where *M* is the average molar mass of the mixture.

The conversion to molar concentration *c _{i}* is given by:

or

where *M* is the average molar mass of the solution, *c* is the total molar concentration and *?* is the density of the solution.

The mole fraction can be calculated from the masses *m _{i}* and molar masses

In a spatially non-uniform mixture, the mole fraction gradient triggers the phenomenon of diffusion.

- ^
^{a}^{b}^{c}IUPAC,*Compendium of Chemical Terminology*, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "amount fraction". **^**Zumdahl, Steven S. (2008).*Chemistry*(8th ed.). Cengage Learning. p. 201. ISBN 0-547-12532-1.**^**Rickard, James N.; Spencer, George M.; Bodner, Lyman H. (2010).*Chemistry: Structure and Dynamics*(5th ed.). Hoboken, N.J.: Wiley. p. 357. ISBN 978-0-470-58711-9.**^**Thompson, A.; Taylor, B. N. "The NIST Guide for the use of the International System of Units". National Institute of Standards and Technology. Retrieved 2014.

This article uses material from the Wikipedia page available here. It is released under the Creative Commons Attribution-Share-Alike License 3.0.

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